ammonium persulfate cas no

Ammonium persulfate: . More info about absorbents, including situations to watch out for National Oceanic and Atmospheric Administration. : A3678 : Sigma : 016-060-00-6 : 7727-54- 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Synthesis of substances 1.3 Details of the supplier of the safety data sheet Company Telephone Fax Specific target organ toxicity \u2013 single exposure, Category 3, H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. volumes of water, neutralized and flushed to sewer. 10, 470]. Carefully collect remainder. : AC401160000; AC401160020; AC401160050; AC401160100;AC401160250; AC401161000; AC401165000 CAS No 7727-54- Synonyms Ammonium peroxydisulfate; Peroxydisulfuric acid diammonium saltRecommended Use Laboratory chemicals. Do not induce vomiting. Component CAS-No Weight % Ammonium persulfate 7727-54- >95 4. 7727-21-1 3D model . P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. [8] For example, in the Minisci reaction and Elbs persulfate oxidation, Airborne dust containing ammonium persulfate may be irritating to eye, nose, throat, lung and skin upon contact. Sore throat. Platelike or prismatic (monoclinic) crystals, or white granular powder. Do NOT let this chemical enter the environment. listed below. Ammonium persulfate (APS) is an oxidizing agent that is often used with tetramethylethylenediamine (TEMED, Part No. other persulfates such as potassium persulfate. : 1336-21-6. 17919) to catalyze the polymerization of acrylamide and bisacrylamide to prepare polyacrylamide gels for electrophoresis. Fresh air, rest. Dry. : 1336-21-6. Ammonium persulfate is a colorless or white Molecular mass: 228.2 UN Classification Description SDS Pricing; 338818: 28% NH 3 in H 2 O, 99.99% trace metals basis: Expand. The solution in water is a medium strong acid. Common Name: AMMONIUM PERSULFATE Synonyms: Ammonium Peroxydisulfuric Acid; Diammonium Persulfate . Risk of fire and explosion on contact with combustible substances or . Belongs to the Following Reactive Group(s), U.S. Bu. NH3, and NOx. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. [2][3] The method was first described by Hugh Marshall. listed below. Use water in flooding quantities as fog. Handle in accordance with good industrial hygiene and safety practice. Avoid formation of dust and aerosols. Immediately flush contaminated eyes with gently flowing water. Food Additives: FLOUR_TREATMENT_AGENT, 8F, Block C, No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030, China. explosive. [4], The ammonium, sodium, and potassium salts adopt very similar structures in the solid state, according to X-ray crystallography. Special Hazards of Combustion Products: Toxic oxides of nitrogen and sulfuric acid fumes may form in fire. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Ammonium persulfate is a standard ingredient in hair bleach. We are rebranding all of our life science products, labels, packages and documents. Our portfolio of innovative products, services and solutions. Mines approved toxic dust mask; chemical goggles; rubber gloves; neoprene-coated shoes (USCG, 1999). A powdered mixture with aluminum and water can explode [NFPA 491M 1991]. If you are human user receiving this message, we can add your IP address to a set of IPs that can access FederalRegister.gov & eCFR.gov; complete the CAPTCHA (bot test) below and click "Request Access". Do not contaminate water, foodstuffs, feed or seed by storage or disposal. An official website of the United States government. Refer for medical attention . Polymeric Microspheres and Magnetic Beads, Novabiochem Peptide and DNA Synthesis Reagents, Analytics and Sample Preparation Services, BioReliance Cell and Gene Therapy Testing Services, Calibration, Verification and Suitability Testing, Process Solutions: Portfolio Announcements, Ammonium persulfate, Peroxidisulfuric acid diammonium salt. with the financial assistance of the European Commission. Transportation In the ammonium salt, the O-O distance is 1.497. 2023 Merck KGaA, Darmstadt, Germany and/or its affiliates. Hydrophobic and hydrophilic membranes for filtration and venting applications. Gives off irritating or toxic fumes (or gases) in a fire. Carefully collect remainder. Stable under recommended storage conditions. AMMONIUM PERSULFATE is a potent oxidizing agent. Contact with dust irritates eyes and causes skin rash. 10, 470]. Use local exhaust or breathing protection. CAS Number: 7727-54-. Can be used as surface treatment agent of metal and semiconductor, etchant of printed circuit. The substance is harmful to aquatic organisms. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{"a]f&&CY].dR{;?j}J3]0{ ?>]|YlbE#SsBsz/E8^,e^ny~]p>y$T7E;8>0?=s'swn|'}+d {_q aoR}?0}5_ofG{_I !|l:x}@#a/SSIg_>/;%_m4gwr5Pm v-Y ~|eHw4.cCi3Av:aBJ}]El*Hu:;N! Inhalation of dust may cause asthma-like reactions. Ammonium persulfate is used as a hair [10] Furthermore, it has been suggested that exposure to ammonium persulfate can cause asthmatic effects in hair dressers and receptionists working in the hairdressing industry. It can decompose of oxygen when high heat; it can generate toxic nitrogen oxides, sulfur oxides and ammonia fumes when heated. Apply water from as far a distance as possible. Turrentine weighed copper spirals before placing the copper spirals into the ammonium persulfate solution for an hour. r+o+bvK.|wpYyhA?i. 10, 470]. Exposure to high levels of dust may cause difficulty in breathing. If in solution, reacts violently with iron, powdered aluminium and silver salts. Avoid dust formation. It is a colourless (white) salt that is highly soluble in water, much more so than the related potassium salt. Properties grade reagent grade Quality Level 100 vapor density 7.9 (vs air) Assay 98% known to react with the [O-]S(=O)(=O)OOS(=O)(=O)[O-], Except where otherwise noted, data are given for materials in their. Primary and secondary antibodies, blockers and custom services. A strong oxidizing agent. Decomposes in water and moist air, Contributions from the Chemical Laboratory of the University of Edinburgh. Show this safety data sheet to the doctor in attendance. absorbents UN1444 Ammonium persulfate, Hazard Class: Behavior in Fire: Decomposes with loss of oxygen that increases intensity of fire (USCG, 1999). Molecular Formula: H 8 N 2 O 8 S 2. Ammonium persulfate is slightly irritating to eyes and skin in rabbits. Ammonium persulfate (APS) is the inorganic compound with the formula (NH 4) 2 S 2 O 8. AMMONIUM PERSULFATE is a potent oxidizing agent. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). It can be used as analytical reagents, photographic fixing agent and reducing agent. /Inorganic acids and related compounds/. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. Stable. A powdered mixture with aluminum and water can explode [NFPA 491M 1991]. Contact with dust irritates eyes and causes skin rash. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. May cause a general allergic reaction, such as urticaria or shock. 2. Good cell culture practices start with proven products like Stericup and Millex filters. Pioneering excellence with Steritest Symbio Pumps. 7727-54-0) SDS. Gloves must be inspected prior to use. Ammonium hydroxide solution. The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. Contact with dust irritates eyes and causes skin rash. 7727-54-0, 7727-21-1, 7775-27-1 Chemical Name Ammonium persulfate, potassium persulfate, sodium persulfate Structural Formula O S O S O O O O O O O S O S O O O O O O O S O S O O O O O O . X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? [1] View Products on Sigmaaldrich.com. Web site owner: F. Feher, "Potassium Peroxydisulfate" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Index-No. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/ P403+P233 Store in a well-ventilated place. Acidic solutions dissolve iron violently, [Mellor, 1947, Vol. Illustrative of its powerful oxidizing properties, ammonium persulfate is used to etch copper on printed circuit boards as an alternative to ferric chloride solution. This experiment was extended to other metals such as nickel, cadmium, and iron, all of which yielded similar results. Remove contact lenses, if present and easy to do. Due to aggressive automated scraping of FederalRegister.gov and eCFR.gov, programmatic access to these sites is limited to access to our extensive developer APIs. Copyright 2006-2023 Thermo Fisher Scientific Inc. All rights reserved, Spectroscopy, Elemental and Isotope Analysis, Gel Electrophoresis Equipment and Supplies, Protein Electrophoresis & Western Blotting. Special Hazards of Combustion Products: Toxic oxides of nitrogen and sulfuric acid fumes may form in fire. forming oxygen gas. Fast, safe transfer of plates to isolator. CAS No. Not combustible but enhances combustion of other substances. CAS Number. Then wash away with plenty of water. If material involved in fire: Cool all affected containers with flooding quantities of water. Continue rinsing. Wear self-contained breathing apparatus for firefighting if necessary. Highlights: Name: Ammonium persulfate (APS) Formula: (NH 4 )2S 2 O 8. : 7727-54- 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Inhalation: LC50 Rat inhalation >2950 mg/cu m 4 hr, Toxicity to daphnia and other aquatic invertebrates: no data available, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. First-aid measures General Advice If symptoms persist, call a physician. Routes of exposure It is a strong oxidizing agent that is used as a catalyst in polymer chemistry, as an etchant, and as a cleaning and bleaching agent. Give one or two glasses of water to drink. Please enter a quantity of 1 or more to add items to your cart. Inhalation risk Uses. A white crystalline solid. <> Hide. water-sensitive explosive); aluminum powder. A strong oxidizing agent. Properties of Ammonium persulfate Melting Point: 120 C Density: 1.98 Physical Appearance: Off-white crystalline powder known to react with the 1. p. 390. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Thermo Scientific Pierce Ammonium Persulfate (APS) is an oxidizing agent that is used with TEMED to catalyze the polymerization of acrylamide and bisacrylamide to prepare polyacrylamide gels for electrophoresis. Ullmann's Encyclopedia of Industrial Chemistry, "Electroreduction of Peroxodisulfate: A Review of a Complicated Reaction", "LXXIV. Repeated or prolonged contact with skin may cause dermatitis. chemicals, and to make dyes. The substance is irritating to the eyes, skin and respiratory tract. ILO and WHO 2021. (Select up to 3 total.) It is strong oxidant, it can explode when mixed with reducing agent, sulfur, phosphorus etc; it can explode when be heated, impacted, and meet fire. P337+P313 If eye irritation persists: Get medical advice/attention. Ammonium peroxodisulfate MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. When heated to decomposition it emits toxic fumes of /sulfur oxides, nitrogen oxides and ammonia/. Used for detection and determination of manganese and iron. Gives off irritating or toxic fumes (or gases) in a fire. It is soluble in water, the solubility is 58.2g/100ml water at 0. CAS No. A white crystalline solid. Dry. 1 0 obj << /Type /Page /Parent 593 0 R /Resources 2 0 R /Contents 3 0 R /MediaBox [ 0 0 612 792 ] /CropBox [ 0 0 612 792 ] /Rotate 0 >> endobj 2 0 obj << /ProcSet [ /PDF /Text ] /Font << /TT2 622 0 R /TT4 627 0 R /TT5 574 0 R /TT7 575 0 R >> /ExtGState << /GS1 628 0 R >> /ColorSpace << /Cs6 623 0 R >> >> endobj 3 0 obj << /Length 2752 /Filter /FlateDecode >> stream Extinguish fire using agent suitable for type of surrounding fire. After an hour, the spirals were weighed again and the amount of copper dissolved by ammonium persulfate was recorded. CAS No. Refer for medical attention. Ammonia solution 25%. CAS No. y/8U;$~h>8U?>3q2 6 Q6a*O=~ltt[?u[fp~X` m>~G\u^d Ensure adequate ventilation. It gradually loses NH3 on exposure to air. Find huge list of ammonium persulfate (cas no 7727-54-0), ammonium persulfate manufacturers, ammonium persulphate suppliers and exporters. These asthmatic effects are proposed to be caused by the oxidation of cysteine residues, as well as methionine residues. Fresh air, rest. and hair bleaches. A powdered mixture with aluminum and water can explode [NFPA 491M 1991]. with sulfuric acid is a strong oxidzing No. production of metals, textiles, photographs, cellophane, It is also used as an P272 Contaminated work clothing should not be allowed out of the workplace. Optimize your QC lab workflow and ensure regulatory compliance. This substance is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at 10 000 to < 100 000 tonnes per annum. USA.gov. More info about absorbents, including situations to watch out for A white crystalline solid. HWn}W#YX4gx2(Z NTKy(@KF&w_lS\mbpX(!~ e!uDJ8 2%IPe=8:aa.=ixaw%\Cy>Faaf~j^A)*c'ibhb1Xi2H It can be used to prepare aniline dyes and dye oxidation and electroplating industry, photographic industry and chemical analysis. A mixture with sodium peroxide will explode if subjected to friction (crushing in a mortar), heating, or if a stream of carbon dioxide is passed over it [Mellor 10:464 1946-47]. Compare Product No. UN Hazard Class: 5.1; UN Pack Group: III, Prepared by an international group of experts on behalf of ILO and WHO, It is a strong oxidizing agent that is used as a catalyst in polymer chemistry, as an etchant, and as a cleaning and bleaching agent. rubber, adhesive papers, foods, soaps, detergents, and Material itself does not burn or burns with difficulty.AMMONIUM PERSULFATE is a potent oxidizing agent. A mixture with sodium peroxide will explode if subjected to friction (crushing in a mortar), heating, or if a stream of carbon dioxide is passed over it [Mellor 10:464 1946-47]. dermatitis and represents a major allergen in hairdressers. endobj Rat LD50: 689 mg/kg; intraperitoneal-rat LD50: 226 mg/kg. cleaning solution. This Website requires your browser to be JavaScript enabled. APt/:=J7U{{P#vpItx%JGaU>>|;yCbkmSpO=r<=.xf}|gjtu{zn58/Y[T;!;p'Q^ Lw. Mixtures: 016-060-00-6 Not applicable SECTION 4: First aid measures 4.1. hair bleaches. Uses. : 016-060-00-6 CAS-No. Potassium persulfate is the inorganic compound with the formula K 2 S 2 O 8. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, Ionization Energy/Potential: data unavailable. Training programs and seminars designed for you. CAS #: 7727-54-0: UN #: 1444 EC Number: 231-786-5 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Not combustible but enhances combustion of other substances. First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Your fast track through regulatory challenges.. Functional excipients to enhance bioavailability. Effects of short-term exposure P271 Use only outdoors or in a well-ventilated area. CAS No. react vigorously with reducing agents. 7727-54-0) SDS, Recommended use of the chemical and restrictions on use, Classification of the substance or mixture, GHS label elements, including precautionary statements, Other hazards which do not result in classification, Description of necessary first-aid measures, Most important symptoms/effects, acute and delayed, Indication of immediate medical attention and special treatment needed, if necessary, Specific hazards arising from the chemical, Special protective actions for fire-fighters, Personal precautions, protective equipment and emergency procedures, Methods and materials for containment and cleaning up, Conditions for safe storage, including any incompatibilities, Individual protection measures, such as personal protective equipment (PPE), Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code, Safety, health and environmental regulations specific for the product in question, For industry use only. Not for use in diagnostic procedures. V. The trisulphates", "Action of Ammonium Persulphate on Metals", "Ammonium persulfate can initiate an asthmatic response in mice", https://en.wikipedia.org/w/index.php?title=Ammonium_persulfate&oldid=1134627221, This page was last edited on 19 January 2023, at 17:17. When heated to 120 C, it can decompose, it is easily damped and it can cake in moist air. Together. Inhalation produces slight toxic effects. Names and Identifiers Properties Safety and Handling Computational chemical data 325 Suppliers. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Avoid breathing dust. Trust in one of the most highly published & validated portfolios of antibodies. It is also used as polymerization initiator, desizing agent in fiber industry. PRODUCT AND COMPANY IDENTIFICATION AMMONIUM PERSULFATE 7727-54-0Ammonium Peroxydisulfate; Diammonium Peroxydisulphate; Peroxydisulfuric acid,diammonium salt; Peroxydisulfuric acid, ammonium salt Recommended use of the chemical and restrictions on use It can be used as metal etchant, circuit board cleaning and etching, copper and aluminum surface activation, modified starch, pulp and textile bleaching at low temperature and desizing, circulating water purification treatment systems, oxidative degradation of harmful gases, low formaldehyde adhesive stick bound to accelerate, disinfectants, hair dye decolorization. The quantity field is empty. It is mainly used as an oxidizing agent and the preparation of hydrogen peroxide, potassium persulfate and other persulfate. Oxidizing. Do not eat, drink, or smoke during work. Do NOT absorb in saw-dust or other combustible absorbents. Ammonium persulfate (APS) is the inorganic compound with the formula (NH4)2S2O8. (USCG, 1999). Rinse contaminated clothing with plenty of water because of fire hazard. Gives off irritating or toxic fumes (or gases) in a fire. Ammonium persulfate can be . It may induce irritant agents; organic and combustible materials. Older eye and skin irritation studies on the Sweep up and shovel. by ingestion. << Operating in the U.S. & Canada as MilliporeSigma. Use caution: Liquids with this reactive group classification have been Acidic solutions dissolve iron violently, [Mellor, 1947, Vol. CAS #: 7727-54- Molar Mass: 228.20 g/mol Chemical Formula: (NH)SO Hill Formula: HNOS. CAS Number UN/NA Number; 7727-54-0; 1444; DOT Hazard Label USCG CHRIS Code; Oxidizer; APE; NIOSH Pocket Guide International Chem Safety Card; none: AMMONIUM PERSULFATE; . Ammonium persulfate (CAS No. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. Does not burn readily, but may cause spontaneous ignition of organic materials. Effects of long-term or repeated exposure Ammonium persulfate ACS reagent, 98.0%; CAS Number: 7727-54-0; EC Number: 231-786-5; Synonyms: AP,APS,Ammonium peroxodisulfate,Ammonium peroxydisulfate,PER; Linear Formula: (NH4)2S2O8; find Sigma-Aldrich-248614 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich . In solution, the dianion dissociates into radicals:[1]. : 7727-54- Use: Ammonium persulfate is widely used in storage battery industry as oxidant and bleaching agent. A mixture with sodium peroxide will explode if subjected to friction (crushing in a mortar), heating, or if a stream of carbon dioxide is passed over Ammonium persulfate [Mellor 10:464 1946-47]. Thermo Fisher Scientific. Cough. No smoking. Ammonium persulfate. CAS Name Ammonium persulfate Molecular Formula H 3 N. 1 / 2 H 2 O 8 S 2 Discover more in SciFinder n. Cite this Page Ammonium persulfate.

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